If there are no lone pairs then the molecular geometry matches the electronic and is octahedral. Octahedral molecular geometry describes the shape of compounds wherein six atoms or groups of atoms or ligands are symmetrically arranged around a central atom. Name molecule and electron geometries for molecules with up to six electron groups surrounding a central atom. Octahedral molecular geometry is one of the molecular geometries in which atoms are arranged symmetrically in 3D space. octahedral. An example of an octahedral compound is molybdenum hexacarbonyl (Mo(CO) 6). There is no reason to tweak the bonds to other values. Octahedral molecular geometry (square bipyramidal shape) describes the shape of compounds where six atoms or ligands are symmetrically arranged around a central atom. There is one central atom and six atoms, molecules, or ligands are arranged around the central atom. In chemistry, octahedral molecular geometry describes a molecular geometry in which 6 ligands are symmetrically arranged around a central atom in an octahedral geometry. Back to top; Molecular Geometry Overview; Shapes of Molecules and Ions In chemistry, octahedral molecular geometry describes the shape of compounds where in six atoms or groups of atoms or ligands are symmetrically arranged around a central atom, defining the vertices of an octahedron. The octahedron has eight faces, hence the prefix octa. Recognize the difference between electron and molecular geometry. Bl3 SF6 CO2 H2S See the answer. This problem has been solved! Solution for Determine which compound should have a(n) octahedral molecular geometry. The shape of the orbitals is octahedral. Compare bond angle predictions from the VSEPR-based model to real molecules. Question: What Is The Molecular Geometry Of The BF4 ? Expert Answer . Molecular Geometry: The Lewis structure of a covalent molecule, describes its geometry in terms of the arrangement of bonding and non-bonding electrons present between the connected atoms. The sulfur hexafluoride (SF 6), with six bonding pairs, is predicted and found to be a regular octahedron. Octahedral molecular geometry (square bipyramidal shape) describes the shape of compounds where six atoms or ligands are symmetrically arranged around a central atom. Show transcribed image text. generic formula: AX 6. example: sulfur hexafluoride SF 6. It has 8 faces, therefore the prefix octa is given. Recognize that molecule geometry is due to repulsions between electron groups. The base bond angles are 180° and 90°. The sulfur hexafluoride (SF 6), with six bonding pairs, is predicted and found to be a regular octahedron. Since there is an atom at the end of each orbital, the shape of the molecule is also octahedral. Previous question Next question Transcribed Image Text from this Question. 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