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Elimination Reactions Elimination reactions are the opposite of addition reactions. 143 7.3 Possible Mechanisms for Substitution Reactions Concerted – bond making and bond breaking processes occur in the same mechanistic step with no intermediate. 7) respect to substitution reactions. 129 0 obj <>
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764 CHAPTER 16 • THE CHEMISTRY OF BENZENE AND ITS DERIVATIVES These directing effects occur because electrophilic substitution reactions at one position of a benzene derivative are much faster than the same reactions at another position.That is, the substitution reactions at the different ring positions are in competition.For example, in Eq. stream 0000167029 00000 n
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Benzenes : Page 4 The General Mechanism for Electrophilic Aromatic Substitution: • The rate determining step (R.D.S.) Reactions of Coordination Compounds CHEM 462 December 6th T. Hughbanks Ligand Substitution Reactions Reminders: kinetic terms: Labile vs. Substitution reactions occur when two starting materials exchange groups to form two new products. /Type /XObject 0000192133 00000 n
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/Title (�� F r e e r a d i c a l s u b s t i t u t i o n r e a c t i o n p d f) is the reaction between the benzene and the electrophile, the benzene is the Lewis Base/Nucleophile in the R.D.S. endobj Free radical substitution reaction pdf Chapter 4: Alcohol and Alkyl Halides Radical Replacement Mechanism Unlike the vast majority of reactions that you will see in your organic chemistry course, radical mechanisms require that fish curly arrows that represent the movement of … Introduction to Substitution Reactions in Organic Chemistry Notes pdf ppt Substitution Reaction: Substitution reaction (also known as single displacement reaction or single replacement reaction) is a chemical reaction during which one functional group in a chemical compound is replaced by another functional group. 0000163153 00000 n
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