; Golovnya, R.V., Variation in retention indices and equivalent chain lengths of homologous series of n-alkyl acetates, n-alkyl methyl ketones, and methyl esters of aliphatic carboxylic acids as a function of homolog number and analysis temperature, Zh. Chromatogr., 101, 1974, 103-123. umn class: Standard non-polar; Column type: Capillary; CAS no: 554121; Active phase: SE-30; Data type: Kovats RI; Authors: Chretien, J.R.; Dubois, J-E., Topological Analysis: A Technique for the Physico-Chemical Exploitation of Retention Data in Gas-Liquid Chromatography, J.     P = vapor pressure (bar) ; Hierro, E.M.; de la Hoz, L.; Mottram, D.S. Industrially, it is prepared by carboalkoxylation, i.e., the reaction of ethylene with carbon monoxide and methanol in the presence of a catalyst: The reaction is catalyzed by nickel carbonyl and palladium(0) complexes. Go To: Top, Phase change data, References, Notes. Food Chem., 49, 2001, 1364-1369. ass: Standard polar; Column diameter: 0.25 mm; Column length: 60 m; Column type: Capillary; Heat rate: 3 K/min; Start T: 40 C; End T: 190 C; Start time: 6 min; CAS no: 554121; Active phase: HP-Wax; Carrier gas: He; Phase thickness: 0.5 um; Data type: Normal alkane RI; Authors: Sanz, C.; Maeztu, L.; Zapelena, M.J.; Bello, J.; Cid, C., Profiles of volatile compounds and sensory analysis of three blends of coffee: influence of different proportions of Arabica and Robusta and influence of roasting coffee with sugar, J. Sci. Chromatogr., 319, 1985, 131-142. umn class: Standard polar; Column diameter: 0.23 mm; Column length: 46 m; Column type: Capillary; Start T: 100 C; CAS no: 554121; Active phase: SP-1000; Carrier gas: N2; Data type: Kovats RI; Authors: Horna, A.; Taborsky, J.; Churacek, J.; Dufka, O., Chromatography of monomers. Transl. Rinse mouth. Timmermans, J.; Mattaar, J.F., UN Classification Guthrie, J.P.; Cullimore, P.A., [all data], Young and Thomas, 1893 Boiling point: 80°C Melting point: -88°C Relative density (water = 1): 0.92 Solubility in water, g/100ml at 25°C: Vapour pressure, kPa at 20°C: 8.5 Relative vapour density (air = 1): 3 Relative density of the vapour/air-mixture at 20°C (air = 1): 1.2Flash point: -2°C c.c.Auto-ignition temperature: 469°C Explosive limits, vol% in air: 2.5-13.0Octanol/water partition coefficient as log Pow: 0.82. Munch, J.C., Missed the LibreFest? A, 858, 1999, 187-199. ass: Standard non-polar; Column diameter: 0.25 mm; Column length: 60 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 100 C; End T: 260 C; CAS no: 554121; Active phase: RTX-1; Carrier gas: He; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Restek, Restek International, 1999 Product Guide, 1(1), 1999, 578-591, In original 578-591. class: Standard non-polar; Column diameter: 0.32 mm; Column length: 60 m; Column type: Capillary; Description: 40 0C (10 min) 40 - 80 0C at 2 0C/min 80 - 200 0C at 5 0C/min 200 0C (10 min); CAS no: 554121; Active phase: DB-1; Carrier gas: N2; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Yen, G.-C.; Lin, H.-T., Changes in volatile flavor components of guava juice with high-pressure treatment and heat processing and during storage, J. Agric. with the development of data collections included in errors or omissions in the Database. This produces irritating fumes. Chem. Enthalpy of vaporization (at saturation pressure) Effects of long-term or repeated exposure. J. Org. Food Chem., 49, 2001, 5929-5933. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; CAS no: 554121; Active phase: RTX-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Wentworth, W.E. ; Amis, E.S., J. Environ. ; Goodner, K.L., Volatile components in aqueous essence and fresh fruit of Cucumis melo cv. Data from NIST Standard Reference Database 69: The National Institute of Standards and Technology (NIST) Data, 1989, 34, 247. binary mixtures and chemical reactions, SRSD 2 – Web Thermo Tables (WTT), "lite" edition, SRSD 3 – Web Thermo Tables (WTT), professional edition, SRD 156 – Clathrate Hydrate Physical Property Database. Fette, Seifen, Anstrichm., 1953, 55, 217-24. umn class: Standard non-polar; Column type: Capillary; Start T: 333 C; CAS no: 554121; Active phase: OV-1; Data type: Kovats RI; Authors: Hu, X.-F.; Lu, C.-H.; Yin, C.-S., Modeling Gas Chromatographic Retention Indices of Oxygen-containing Compounds by Novel Atom-type Topological Indices, Chinese Journal of Chemical Physics, 19(3), 2006, 243-247. umn class: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Start T: 70 C; CAS no: 554121; Active phase: Apiezon L + KF; Phase thickness: 0.06 um; Data type: Kovats RI; Authors: Svetlova, N.I. ; Jurs, P.C. (TRC) data available from this site, much more physical Chromatogr., 11, 1963, 463-471. ; Jurs, P.C. Scand., 1954, 8, 1086. Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Food Microbiol., 85, 2003, 111-125. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 60 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 40 C; End T: 280 C; Start time: 2 min; CAS no: 554121; Active phase: CP-Sil 8CB-MS; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Bruna, J.M. ; Yang, Z.C. All rights reserved. Formula: C4H8O2 / C2H5COOCH3 ; Yang, Z.C. National Institute of Standards and [all data], Svoboda, Vesely, et al., 1977 ; Roux-Desgranges, G.; Grolier, J.-P.E., shall not be liable for any damage that may result from Commun., 1965, 30, 3526-8. Database and to verify that the data contained therein have [all data], Timmermans and Hennaut-Roland, 1959 Chromatogr., 262, 1983, 316-320. umn class: Standard non-polar; Column diameter: 0.3 mm; Column length: 25 m; Column type: Capillary; Start T: 80 C; CAS no: 554121; Active phase: OV-101; Carrier gas: N2; Data type: Kovats RI; Authors: Haken, J.K.; Korhonen, I.O.O., Gas chromatography of homologous esters. Bull. It undergoes vapour-phase aldol condensation with formaldehyde to form methyl methacrylate . © 2018 by the U.S. Secretary of Commerce It is a colorless liquid with a fruity, rum-like odor.[2]. SRD 103b – Thermo Data Engine (TDE) for pure compounds, J. Chem. [all data], Lecat, 1926 in these sites and their terms of usage. Soc. Food Chem., 49, 2001, 1345-1352. class: Semi-standard non-polar; Column diameter: 0.32 mm; Column length: 50 m; Column type: Capillary; Description: 0 0C (8 min) -> (1 min) -> 50 0C (2 min) ^ 2.5 0C/min -> 100 0C ^ 6 0C/min -> 250 0C; CAS no: 554121; Active phase: BPX-5; Carrier gas: He; Phase thickness: 0.50 um; Data type: Linear RI; Authors: Bauchot, A.D.; Mottram, D.S. Physical State; Appearance Food Chem., 29, 1981, 316-321. class: Standard non-polar; Column diameter: 0.53 mm; Column length: 60 m; Column type: Capillary; Description: 40C(6min)=>5C/min=>80C=>10C/min=>200C; CAS no: 554121; Active phase: SPB-1; Carrier gas: He; Phase thickness: 5 um; Data type: Normal alkane RI; Authors: Flanagan, R.J.; Streete, P.J. © 2018 by the U.S. Secretary of Commerce Czech. Res. Anal. Z. Phys. Remove contaminated clothes. Then store and dispose of according to local regulations. and chemical property data is available from the Uchebn. V. Influence of electronic effects and column polarity on retention index, J. Chromatogr. New experimental determinations., ; Stearns, S.D., Multiple detector responses for gas chromatography peak identification, J. Chromatogr. uses its best efforts to deliver a high quality copy of the Chromatogr., 240, 1982, 423-444. umn class: Standard non-polar; Column type: Packed; Start T: 70 C; CAS no: 554121; Active phase: SE-30; Data type: Normal alkane RI; Authors: Yabumoto, K.; Jennings, W.G. methyl propionate. Sci., 39, 2007, 563-572. ass: Standard polar; Column diameter: 0.25 mm; Column length: 60 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 40 C; End T: 250 C; CAS no: 554121; Active phase: CP-Wax 52CB; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Kourkoutas, D.; Elmore, J.S. ; de Pooter, H.L. [all data], Hurd, Perletz, et al., 1945 ; Syomina, L.A.; Samusenko, A.L., Nonlinear variation of sorption parameters of n-alkane homologs in temperature-programmed gas chromatography (TPGC) and new equation for calculation of retention indices, J. Hi. Chim. ; Klimova, T.F., Constant pressure heat capacity of liquid, Enthalpy of combustion of liquid at standard conditions, Enthalpy of vaporization at standard conditions. Faraday Soc., 1947, 43, 356. Food Chem., 50, 2002, 5386-5390. class: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Description: 40C (6min) => 2.5C/min => 150C => 90C/min => 250C; CAS no: 554121; Active phase: HP-5; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Jordan, M.J.; Shaw, P.E. Ber., 1955, 88, 583. CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. Acta Chem. [all data], Goldschmidt and Dachs, 1955 Chem. Abt. National Institute of Standards and DH - Eugene S. Domalski and Elizabeth D. Hearing, Go To: Top, Condensed phase thermochemistry data, References, Notes, Data compiled as indicated in comments: Gas-liquid chromatographic studies of C1-C6 n-alkyl and C3-C6 isoalkyl acrylates and their hydrogen halide and halogen addition derivatives, J. ; Paz Andrade, M.I. Appearance: Methyl propionate, 99%; Methyl propionate, 99%; colourless to pale yellow liquid with a fruity, rum odour; colourless liquid, Solubility: Water, 6.24e+004 mg/L (25 deg C). Agric. Refer for medical attention . ; Golovnya, R.V. [all data], Gartenmeister, 1886 Data Program, but require an annual fee to access. ; Herve, C.; Richoux, R.; Lortal, S., Varied volatile compounds are produced by Propionibacterium freudenreichii in Emmental cheese, Food Chem., 87, 2004, 439-446. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 5 K/min; Start T: 50 C; End T: 280 C; End time: 10 min; Start time: 0.5 min; CAS no: 554121; Active phase: HP-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Guillen, M.D. Help. Transportation Food Chem., 33(2), 1985, 249-254. ass: Standard non-polar; Column type: Capillary; CAS no: 554121; Active phase: OV-1; Data type: Normal alkane RI; Authors: Ramsey, J.D. TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director NIST subscription sites provide data under the ; Ding, S.F. SRD 103a – Thermo Data Engine (TDE) for pure compounds. Vyssh. Belg., 1921, 30, 213. Chromatogr., 348, 1985, 141-149. umn class: Standard polar; Column length: 2 m; Column type: Packed; Start T: 100 C; CAS no: 554121; Active phase: Carbowax 20M; Substrate: Chromosorb W; Data type: Kovats RI; Authors: Zarazir, D.; Chovin, P.; Guiochon, G., Identification of hydroxylic compounds and their derivatives by gas chromatography, Chromatographia, 3, 1970, 180-195. umn class: Standard polar; Column length: 2 m; Column type: Packed; Start T: 170 C; CAS no: 554121; Active phase: Polyethylene Glycol; Carrier gas: He; Substrate: Celite 545 (0.20-0.50 mm); Data type: Kovats RI; Authors: Shashkova, A.A.; Znamenskaia, A.P. It is commonly used in organic synthesis. NIST Standard Reference Remove all ignition sources. The vapour pressures, molecular volumes, and critical constants of ten of the lower esters, TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director XXVII. Cool.     T = temperature (K). Structure-retention increments of aliphatic esters, J. The purpose of the fee is to recover costs associated Have questions or comments? Molecular mass: 88.1 Chromatogr., 158, 1978, 43-56. umn class: Standard non-polar; Column length: 2 m; Column type: Packed; Start T: 100 C; CAS no: 554121; Active phase: SE-30; Substrate: Chromosorb W; Data type: Kovats RI; Authors: Zarazir, D.; Chovin, P.; Guiochon, G., Identification of hydroxylic compounds and their derivatives by gas chromatography, Chromatographia, 3, 1970, 180-195. umn class: Semi-standard non-polar; Column diameter: 0.321 mm; Column length: 60 m; Column type: Capillary; Start T: 80 C; CAS no: 554121; Active phase: DB-5; Carrier gas: N2; Phase thickness: 0.25 um; Data type: Kovats RI; Authors: Mijin, D.; Antonovic, D.G., The temperature dependence of the retention index for n-alkyl esters of acetic, propionic, cyclohexanecarboxylic, benzoic and phenylacetic acid on DB-1 and DB-5 capillary columns, J. Serb.

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