I����АF2�KOf���j'S�" �q�ߏ Introduction. – Aldehydes & Ketones �V ��ޔ��{. <> CIE A-Level 18: Carbonyl Compounds Notes: 18.1 Introduction to Aldehydes and Ketones; 18.2 Reactions of Aldehydes and Ketones The periodic table—the transition metals, Topic 11: Measurement and data processing, 3. ùm�g�`�C�A ��_~����}��J? 18 Carbonyl Compounds (Notes for aldehyde and ketones) (Notes 2), In short, carbonyl compounds can be divided into two major groups ��a`��x$u�: �(!<8JX�$�d�m̚��X�Dȥ�M�!̔��"�6"�$�R�'s��W��6h���f�yQMY>�"e�`@�J��cK{��e�ŝ2 W�J�M�t�0�$�/�~/1�.I�����Q��2ܲz %���� <> CIE A-Level 18: Carbonyl Compounds Notes: © 2018 A* Chemistry. {]���=v�q�� endobj tgaC&ש�e�1�ȁ>gߏ(�h*9��*N0g\߮������-����z�6�G��l/���xJ� �׉B� 0���\�� 01�t! These are also used as reagents and solvents. Save my name, email, and website in this browser for the next time I comment. Candidates should be able to: (a) write the general formula for carbonyl compounds: aliphatic and aromatic aldehydes and ketones; (b) name aliphatic and aromatic aldehydes and ketones according to the IUPAC nomenclature; (c) describe structural and optical isomerism in carbonyl compounds; (d) state the physical properties of aliphatic and aromatic aldehydes and … W$u�*2$ͺ�G ���trq &rN�,�L�+�.&�R*%��$ Carbonyls are compounds with a C=O bond. <>>> <>/ExtGState<>/Pattern<>/Font<>/ProcSet[/PDF/Text/ImageB/ImageC/ImageI] >>/MediaBox[ 0 0 960 540] /Contents 4 0 R/Group<>/Tabs/S/StructParents 0>> s��߆BS@��W�6�ˎ�>�T Carbonyl compounds have a general formula CnH2nO and contain a >C=O group which is present in aldehydes H-C=O as well as in R 2 C=O ketones. These have been made according to the syllabus 9701 and cover all the relevant topics for examination in March/June. Ketones, common … �Ɍ�� endobj 3 0 obj They can be either aldehydes or ketones If the C=O is on the end of the chain with an H attached it is an aldehyde. �Y�沄_��0Spcrxk�N��g����͊fg+�&�ǒp���-���XӋF���`M��A����6e�گm��tp�Qj&�^����k�0��,�(P��/�|�����#(r���}@~m�u��j���Y�[`�#t�?6/ȩ�C)O9b\ �/*/�߃P���X`��+|Y8�)��gS�t ���o~���a�5$�1|��Q��]�|�nc�nŰ�1�B��/P͘ X 8��,#\݂1��]W�@Bm�c@X��C�mfM�/:e���${�9�8��Fa|s�� Help your Chemistry students with note taking and keep them engaged. �Go��O��0T�����,L����i���/'���y�����;��3)�卸��_T/� ���ן|���Rn�Y�t�5����=+������Z���-ӶY"�I���ȯE�4Z�AA:{EGǯ�h櫡�J�V�`�)�����v�B!��_��qx ��T�p��`B�(�HJ�'�K%�uw������Y���� They are constituents of fabrics, plastics and drugs. UNIT – III: Carbonyl compounds (Name Reaction) Dr. Sumanta Mondal _ Lecture Notes _Pharmaceutical Organi c Chemistry-I I ( BP 202T)_B.Pharm-II Sem Pa ge | 11 CH3 CH3CH2CH2CH=O CH3CHCH=O butanal 2-methylpropanal H2C=O CH3CH=O methanal ethanal 5. All Rights Reserved. 18 Carbonyl Compounds. 1 0 obj Aldehydes and ketones can be prepared from hydrocarbons by following ways: In short, carbonyl compounds can be divided into two major groups. Saiful Islam BPharm, MSc North South University Fb Group: Pharmacy Universe ... Parent chain = longest continuous carbon chain containing the carbonyl group; alkane, drop –e, add –al. ; The three oxygen sp 2 AO’s are involved as follows: The two unshared electorn pairs of oxygen occupy two of these AO’s, and the third is involved in sigma bond formation to the carbonyl carbon. stream �Y/aT �w�(4aE.u��]������7Ԭed�S��Zh��%�՜����4�)WT�t�����&�� ��& *���m�Rqn����7q�����D$Hj�5O�*XR�EI�F�6��%��� ,uh� ���C6����= Carbonyl Compounds and Nucleophilic Addition Md. 2 0 obj Notes for the CIE O Level Chemistry – 18: Carbonyl Compounds. Both the carbon and oxygen atoms are hybridized sp 2, so the system is planar. endobj (adsbygoogle = window.adsbygoogle || []).push({}); Aldehydes and ketones can be prepared by oxidation of primary and secondary alcohols. Formulae, stoichiometry and the mole concept, 7. %PDF-1.5 ���_�]�_D��G ]�H^�@�3�w;�K*��ia@6�O1� About Us | Contact Us | Privacy Policy | Terms and Conditions | Sitemap, GCSE, IGCSE, A-Level, IB and University Chemistry Resources & Revision for all exam boards, C4: Predicting and Identifying Reactions and Products, C5: Monitoring and Controlling Chemical Reactions, 1: Atomic structure and the periodic table, 2: Bonding, structure, and the properties of matter, 6: The rate and extent of chemical change, Topic 4 – Extracting metals and equilibria, Topic 7 – Rates of reaction and energy changes, Unit 1: Structures, Trends, Chemical Reactions, Quantitative Chemistry and Analysis, Unit 2: Further Chemical Reactions, Rates and Equilibrium, Calculations and Organic Chemistry, Unit 1: CHEMICAL SUBSTANCES, REACTIONS and ESSENTIAL RESOURCES, Unit 2: CHEMICAL BONDING, APPLICATION OF CHEMICAL REACTIONS and ORGANIC CHEMISTRY, Topic 1: Atomic Structure and the Periodic Table, Topic 4: Inorganic Chemistry and the Periodic Table, Topic 5: Formulae, Equations and Amounts of Substance, Topic 19: Modern Analytical Techniques II, Module 1: Development of Practical Skills in Chemistry, Module 5: Physical chemistry and transition elements, 13.

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